Victor Osimhen and his club Napoli will play against former champions Liverpool in group A of the UEFA Champions League.
Napoli who played in the Europa last season are also to face Rangers and Ajax.
Eintracht Frankfurt, who are making their group stage debut, are in the same group as Tottenham.
Bayern Munich, Barcelona and Inter Milan have been drawn in the same group.
Group A: Ajax, Liverpool, Napoli, Rangers
Group B: Porto, Atletico Madrid, Bayer Leverkusen, Club Bruges
Group C: Bayern Munich, Barcelona, Inter Milan, Viktoria Plzen
Group D: Eintracht Frankfurt, Tottenham, Sporting Lisbon, Marseille
Group E: AC Milan, Chelsea, RB Salzburg, Dinamo Zagreb
Group F: Real Madrid, RB Leipzig, Shakhtar Donetsk, Celtic
Group G: Manchester City, Sevilla, Borussia Dortmund, FC Copenhagen
Group H: Paris St-Germain, Juventus, Benfica, Maccabi Haifa
Matches will take place between 6 September and 2 November. This season’s Champions League final will take place at the Ataturk Olympic Stadium in Istanbul, Turkey, on 10 June 2023.